Q.

Ammonia dissociates into N2  and  H2 such that degree of dissociation α is much less than 1 and equilibrium pressure is P0 then the value of α is, if Kp for 2NH3(g)N2(g)+3H2(g)  is 27×108P02 :

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a

0.02

b

104

c

can't be calculated

d

4×104

answer is C.

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Detailed Solution

In the following reaction, we have;

2NH3N2+3H21α α2 3α2 1KP=α2P0×3α2P03P02P02×27×108=α4×2724×P02α=2×102

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Ammonia dissociates into N2  and  H2 such that degree of dissociation α is much less than 1 and equilibrium pressure is P0 then the value of α is, if Kp for 2NH3(g)⇌N2(g)+3H2(g)  is 27×10−8P02 :