Q.

Among the following choose the correct relation regarding negative deviation

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a

Obey Raoult’s law

b

ΔmixH<0

c

ΔmixV<0

d

Ptotal<PA+PB

answer is C.

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Detailed Solution

Negative deviation from Raoult’s law important points

a) ΔHmix<0 , exothermic dissolution, heat is evolved.

b) ΔVmix<0 , Volume is decreased during dissolution.

c) PA<PA0XA;PB<PB0XB

     PA+PB<PA0XA+PB0XB

d) Do not obey Raoult’s law.

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