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Q.

Among the first lines of Lyman, Balmer, Paschen and Brackett series in hydrogen atomic spectra, which has higher energy?

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a

Lyman

b

Balmer

c

Paschen

d

Bracket

answer is A.

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Detailed Solution

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Energy is calculated as using the following expression:

E=13.61n12-1n22

For Lyman series, n1=1 and n2=2

E=13.6112-122        =10.2 eV

For Balmer series, n1=2 and n2=3

E=13.6122-132=1.88 eV

On moving further, the energy value decreases. Therefore, the highest energy corresponds to Lyman series.

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