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Q.

Among the following correct basic strength order is
 i) La(OH)3
ii) Ce(OH)3
 iii) Lu(OH)3

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a

i > ii > iii

b

iii > ii > i

c

i > iii > ii

d

iii > i > ii

answer is A.

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Detailed Solution

As the size of the lanthanoid ions decreases from La³⁺ to Lu³⁺, the covalent character of the hydroxides increases and hence the basic strength decreases. Thus, La(OH)₃ is the most basic whereas Lu(OH)₃ is the least basic.

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