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Q.

Among the following electrolytes which is the most effective coagulating agent for Fe(OH)3 sol.

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a

Na2SO4

b

KCl

c

Na3PO4

d

CH3COONa

answer is C.

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Detailed Solution

According to Hardy-Schulze rule, coagulation becomes more effective on the addition of the higher opposite charged electrolyte in the solution. Fe(OH)3 is a positive charged sole and Na3PO4 is known to be the effective coagulation agent as it has a greater ve charge because of having PO43- that has  3 charge.

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