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Q.

Among the following metal carbonyl carbonyls, the C-O bond is strongest in :

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a

Mn(CO)6+

b

Ti(CO)62

c

Cr(CO)6

d

V(CO)6

answer is A.

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Detailed Solution

Mn(CO)6+ because it exhibits the strongest C=O bond and the weakest m-c bond, as well as the least Mlectron density and sigmoidal electron density.

As the charge on  C.A. ,CO bond strength 

or C-O bond order,   or C-O bond length

Hence correct option A.

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