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Q.

Among the following metal carbonyl, the C-O bond order is lowest in:

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a

Fe(CO)5

b

Mn(CO)6+

c

V(CO)6

d

Cr(CO)6

answer is B.

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Detailed Solution

[V(CO)6]- has the lowest bond order.
V=3d34s2, V-=3d43d44s2
Effective configuration =3d63 lone pair for back bonding with CO.
Three lone pairs for CO back bonding.
Thus, the correct option is B.

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