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Q.

Among the following  number of amines can be prepared by Gabriel’s pththalimide synthesis are….

(i)  (CH3)2CHNH2             (ii)  H3CNHCH2CH3                    (iii)  C6H5NH2                   

 (iv) C6H5CH2NH2       (v)  CH3NH2    (vi)  Question Image
(vii)  Question Image

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answer is 4.

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Detailed Solution

Only 10-alphatic amines can be prepared from Gabriel’s phthalilmidesynthesis, where a halogen is replaced by NH2 group. In cholrobenzene, Cl is attached to sp2hybridized carbon, hence aniline cannot be prepared while halogen atom in 2,4-dinitrochlorobenzene is replaceable, hence compound (vi) can be prepared.

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