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Q.

Among the following, select the disproportionation reaction ?

(i) 2PbNO32   2PbO+ 4NO2 + O2

(ii) I2   I- + IO3-

(iii) 3Cl2 + 6NaOH   5NaCl + NaClO3 + 3H2O

(iv) P4 + 3NaOH + 3H2O  3NaH2PO2 + PH3

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a

All of these

b

(i), (ii), (iii)

c

(ii), (iii), (iv)

d

(i), (iii), (iv)

answer is B.

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Detailed Solution

A reaction in which the same species is simultaneously oxidized as well as reduced is called a disproportionation reaction.

(ii) I20   I--1 + IO3-+5

(iii) 3Cl20 + 6NaOH   5NaCl-1 + NaClO3+5 + 3H2O

(iv) P40 + 3NaOH + 3H2O  3NaH2P+1O4 + P-3H3

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