Q.

Among the following slowest reaction under identical conditions is

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a

AgNO3(aq)+NaCl(aq)AgCl(s)+NaNO3(aq)

b

2KMnO4+5H2C2O4+3H2SO4K2SO4+10CO2+2MnSO4+8H2O

c

H++OH-H2O

d

2KMnO4+10FeSO4+8H2SO4K2SO4+2MnSO4+5Fe2SO43+8H2O

answer is B.

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Detailed Solution

In reaction (A), H+ and OH- are combining to H2O. It is a very fast reaction.

In reaction (B), the KMnO4 reacts as oxidizing agent while the C-C bond of the oxalic acid breaks. But the C-C bond in oxalic acid is a very strong bond due to which the reaction occur at a slow rate.

In reaction (C), the KMnO4 changes Fe2+ to Fe3+. The change of Fe2+ to Fe3+ is a very fast reaction.

Reaction (D) is a precipitation reaction because AgCl is precipitated and it is a very fast reaction.

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