Among the following slowest reaction under identical conditions is

${\mathrm{H}}^{+}+{\mathrm{OH}}^{-}⟶{\mathrm{H}}_2\mathrm{O}$

$2{\mathrm{KMnO}}_4+5{\mathrm{H}}_2{\mathrm{C}}_2{\mathrm{O}}_4+3{\mathrm{H}}_2{\mathrm{SO}}_4⟶$ ${\mathrm{K}}_2{\mathrm{SO}}_4+10{\mathrm{CO}}_2+2{\mathrm{MnSO}}_4+8{\mathrm{H}}_2\mathrm{O}$

$2{\mathrm{KMnO}}_4+10{\mathrm{FeSO}}_4+8{\mathrm{H}}_2{\mathrm{SO}}_4⟶$ ${\mathrm{K}}_2{\mathrm{SO}}_4+2{\mathrm{MnSO}}_4+5{\mathrm{Fe}}_2{\left({\mathrm{SO}}_4\right)}_3+8{\mathrm{H}}_2\mathrm{O}$

${\mathrm{AgNO}}_{3\left(\mathrm{aq}\right)}+{\mathrm{NaCl}}_{\left(\mathrm{aq}\right)}$ $⟶{\mathrm{AgCl}}_{\left(\mathrm{s}\right)}+{\mathrm{NaNO}}_{3\left(\mathrm{aq}\right)}$