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Q.

Among the following statements which one is true?

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a

PH3  is stronger reducing agent than NH3  and it has lower critical temperature than NH3

b

NH3 is more soluble than PH3 in water and HPH>HNH.

c

NH3 is stronger base and stronger reducing agent than PH3

d

NH3 Has higher boiling point than PH3  and has lower melting point than PH3

answer is D.

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Detailed Solution

NH3 is a weak reducing agent than PH3 because XH bond strength decreases down the group. Due to absence of Hbonding, only weak vander waals force of attraction exists in PH3, it has lower critical temperature than NH3.

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