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Q.

Among the following statements,
(A) LiHCO₃ is thermally more stable than Li₂CO₃
(B) Na₂CO₃ is thermally more stable than NaHCO₃
(C) Li₂CO₃ on heating liberates CO₂ but not Na₂CO₃
(D) LiHCO₃ on heating liberates CO₂ but not NaHCO₃

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a

A and D are correct

b

A and C are correct

c

B and C are correct

d

B,C and D are correct

answer is B.

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Detailed Solution

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Among Alkali metal carbonates Li₂CO₃ on heating liberates CO₂

Carbonates are thermally more stable than bicarbonates

All alkalimetal bicarbonates on heating liberates CO₂, H₂O vapour and forms corresponding carbonates

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Among the following statements,(A) LiHCO3 is thermally more stable than Li2CO3(B) Na2CO3 is thermally more stable than NaHCO3(C) Li2CO3 on heating liberates CO2 but not Na2CO3(D) LiHCO3 on heating liberates CO2 but not NaHCO3