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Q.

Among the following, the compound that is readily soluble in water is

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a

BeSO4   

b

 CaSO4   

c

SrSO4

d

BaSO4

answer is A.

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Detailed Solution

Solubility order:

BeSO4>MgSO4>CaSO4>SrSO4>BaSO4
As hydration energy decreases solubility decreases
If anion size is large   SO42,CO32 then with small change in cation size there is no coniderable change in lattice energy then the solubility depends on the hydration energy i.e., here hydration energy dominating factor over lattice energy
With increase in size of cation hydration energy decreases and hence solubility decrerases.
Hydration energy  solubility
BeSO4 readily soluble in water
Where as as BaSO4 is least soluble in water

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