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Q.

Among the following the correct statement(s) is (are): 

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a

All carbon atoms of -CH3 groups do not lie in the same plane in Al2CH36

b

AlCl3 can act as lewis acid in both monomer and dimer form

c

Bridging HbBHb bond is stronger than terminal BHt bond in diborane

d

Maximum six hydrogen atoms lie in the same plane in diborane

answer is A, B.

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Detailed Solution

Question Image

 

 

 

 

 

(non planar molecule)
AlCl3 and Al2Cl6
both have vacant orbitals in central Al atom; and also C.N. of
Al atoms are NOT equal to their maximum value
Terminal B-H bonds are stronger than Bridging B-H bonds
 B2H6is non planar

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