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Q.

Among the following, which has the highest boiling point ?

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a

NH3

b

PH3

c

AsH3

d

CH4

answer is A.

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Detailed Solution

Inter molecular H-bonding increases the boiling point of the compound [ In  NH3]  

Boiling point order :

PH3<AsH3<SbH3<NH3

As the size of central element increases,

molecular size increases, 

intermolecular attractions increases.

Hence ,we need to provide high amount of energy in the form of boiling point [heat],

                   Hence B.Pt increases  form PH3 to SbH3.

Exceptionally hight B.Pt of NH3 is due to its ability to form intermolecular hydrogen bonding.

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