Q.

 Among the following which one does not act as an  intermediate in Hofmann rearrangement? 

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a

 RNCO 

b

 RCON 

c

 RCO NHBr 

d

RNC

answer is D.

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Detailed Solution

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 (ii) RCONHBr+KOHRNCO+KBr+H2O
 (iii) RNCO+2KOHRNH2+K2CO3
RCONH2+Br2+4KOHRNH2+2KBr+K2CO3+2H2O.

Isocyanide is not formed anywhere in the reaction.

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