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Q.

Among the following which statement(s) is/are correct? 

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a

For a liquid in closed vessel at constant temperature 

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b

For KCl solution, limm0ΔTbm is infinity

c

For a solution containing non-electrolyte solute  (Tbm)m0=RMTb01000ΔSVap. Where M is G.M.W of solute in (g), Tb0-Boiling point of pure solvent.

d

0.9 (W/V)%NaCl is called normal saline solution.

answer is C, D.

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Detailed Solution

a) In a closed vessel rate of evaporation is constant because surface area of liquid is constant

b)    ΔTb=Kb.m.i     at any concentration
      lt ΔTbm=Kb.i=2Kbforkcl
  
  mo
c)  Tmmo=Kb=MRTbo21000ΔHval=MRTbo1000ΔSval

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