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Among the given compounds, the most susceptible to nucleophilic attack at the carbonyl group is

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${CH}_{3} COCl$

${CH}_{3} CHO$

${CH}_{3} {COOCH}_{3}$

${CH}_{3} {COOCOCH}_{3}$

answer is A.

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Detailed Solution

The positive charge on carbon is enhanced due to electron-with drawing nature of cholrine.

Acid chlorides are the aldehyde and acid compounds that are most vulnerable to ${Nu}^{⊖}$ assault because

(i) Strong -I effect

(ii) Weak +R effect of Cl atom

(iii) Good leaving group Cl⁻

Because carbonyl carbon has the greatest $e^{⊖}$ deficit, the solution is $C H_{3} C O C l$ .

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