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Q.

Among the isomeric alcohols the boiling points are in the following order

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a

all are same

b

n alcohols > iso - alcohols > neo - alcohols

c

iso - alcohols > n- alcohols > neo - alcohols

d

neo - alcohols > iso - alcohols > n- alcohols

answer is A.

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Detailed Solution

  • The presence of −OH groups in a compound leads to Hydrogen-bonding which greatly increases its boiling point.
  • Primary alcohol has more tendency to form intermolecular H-bond than secondary and tertiary.

Hence the order of B.Ps  is primary > secondary > tertiary

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