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Q.

Among the reactions given below for B2H6, the one which does not take place is

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a

B2H6+HClB2H5Cl+H2

b

2 B2H6+6NH3ΔB3 N3H6 (borazine) 

c

B2H6+2 NCH332CH33NBH3

d

B2H6+6C2H4H3O+3C2H5OH+2 B(OH)3

answer is D.

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Detailed Solution

Reaction between diborane and alkene are carried out in dry ether under an atmosphere of N2 because B2H6 and the products are very reactive. The products further treated with alkaline H2O2 to convert into alcohols.

B2H6+6C2H4BC2H43reactive alkaline H2O2 3CH3CH2OH+H3BO3

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Among the reactions given below for B2H6, the one which does not take place is