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Q.

Among the statement (a)-(d), the incorrect ones are:

(a) Octahedral Co (III) complexes with strong field ligands have very high magnetic moments

(b) When Δ0<P, the d-electron configuration of Co (III) in an octahedral complex is teg4eg2

(c) Wave length of light absorbed by Co(en)33+ is lower than that of CoF63-

(d) If the Δ0 for an octahedral complex of Co (III) is 18,000 cm-1, the Δt for its tetrahedral complex with the same ligand will be 16,000 cm-1

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a

(a) and (d) only


 

b

(c) and (d) only

c

(b) and (c) only

d

(a) and (b) only

answer is A.

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Detailed Solution

In option A number of unpaired electron is 0 and magnetic moment is 0.

In option C , we have (Coen3)3+ which absorbs higher energy than of [Cof6]3−. So, we have the wavelength which is absorbed by [Coen3]3+ which is lower than that of [Cofe6]3−

therefore (c) is correct.According to the equation derived;Δt​=94​Δ0​⇒Δt​=94​×18000=8000cm−1Therefore statement d is incorrect.

Hence, correct option is: (A) (a) and (d) only.

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