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Q.

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Among these compounds the correct order of C-N bond length is :

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a

III>II>I>IV

b

IV>I>II>III

c

III>I>II>IV

d

III>I>IV>II

answer is C.

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Detailed Solution

C- Nbond in (III) is pure single bond so bond length is maximum.
C-N bond in (IV) is pure double bond while in case of (I) and (II) resonance occur so single bond get converted in double bond.

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