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Q.

Among [Ni(CO)4], [Ni(CN)4]-2 and [NiCl4]-2 species the hybridization state of the Ni atom are respectively?

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a

sp3, dsp2, dsp2

b

sp3, dsp2, sp3

c

sp3, sp3, dsp2

d

dsp2, sp3, sp3

answer is B.

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Detailed Solution

  • The [Ni(CO)4] complex has an outermost electronic configuration of 3d24s2 and since CO is a potent ligand, electrons pair up and exhibit sp3  hybridization.  
  • The [Ni(CN)4]-2complex has an outermost electronic configuration of 3d8, and CN since  is a powerful ligand, electrons pair up but one d orbital is vacant and exhibits dsp2 hybridization.
  •  The [Ni(Cl)4]-2 complex's outermost electronic configuration is 3d84s2, and Cl is a weak ligand, therefore electrons are not coupled up and exhibit sp3 hybridization.

Hence, the correct option is option (B) sp3, dsp2, sp3.

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