Q.

Among [Ni(CO)4], [Ni(CN)4]2-and [NiBr4]2- species, the hybridization state of Ni atoms are respectively:

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a

sp3,d2sp,dsp2

b

sp3, dsp2, sp3

c

dsp2, sp3, sp3

d

sp3, sp3, dsp2

answer is B.

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Detailed Solution

The valence electronic configuration of Ni in [Ni(CO)4] is 3d84s2. As CO is a strong ligand, therefore pairing of Ni electrons takes place and the complex has sp3 hybridization.

The valence electronic configuration of Ni in [NiCN4]2-is 3d8. As CN is a strong ligand, therefore pairing takes place and the complex opts dsp2 hybridization.

The valence electronic configuration of Ni in [Ni(Br)4]2- is 3d84s2. As Br is a weak ligand, therefore the electrons of Ni remained unpaired and the complex shows sp3 hybridization.

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