Amongst ${\mathrm{NH}}_3, {\mathrm{PH}}_3, {\mathrm{AsH}}_3 \mathrm{and} {\mathrm{SbH}}_3$ the one with highest boiling point is

As molecular weight increases, magnitude of Van der Waal's force of attraction increases.

Therefore, boiling point increases. Though ${\mathrm{NH}}_3$ has strong H-bonding but boiling point of ${\mathrm{SbH}}_3$ is highest due to highest molecular weight. Boiling point of ${\mathrm{NH}}_3=238.5 \mathrm{K} \mathrm{and} {\mathrm{SbH}}_3 = 254.6 \mathrm{K}.$