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Q.

Amongst the following, the most stable complex is :

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a

CoF63

b

Co(ox)33

c

CoH2O63+

d

Co(ONO)63

answer is B.

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Detailed Solution

Stability order : Co(ox)33>CoH2O63+>Co(ONO)63>CoF63
For a given metal cation and fixed co-ordination number, 5 or 6 membered chelated complex is found to be more stable than complex with monodentate ligand.

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Amongst the following, the most stable complex is :