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Q.

Amongst the various ores of a metal (M) (sulphide carbonates, oxides, hydrated or hydroxides) two ores [X] and [Y] show the following reactivity. 

(a) [X] on calcination gives a black solid (S), water and a colourless gas which produces milkiness when passed through lime water. But this colourless gas does not decolorise acidified KMn04 • 

(b) [X] dissolved in dilute HCl. On reaction with KI gives a white precipitate (P) and iodine ga .... 

(c) [Y] on roasting at high temperature gives metal (M) and a gas  (G1 ) which turns starch iodate solution blue. 

(d) [Y] on reaction with dilute HCl gives a white precipitate (MS) and another gas (G2) which turns lead acetate solution black and also reacts with gas (G1 ) to precipitate colloidal sulphur in presence of moisture. M, S, [X], [Y] gives greenish blue flame.

The gas  (G1 ) can act as:

 

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a

oxidising agent

b

reducing agent 

c

oxidising and reducing agent

d

fluxing agent

answer is C.

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Detailed Solution

Colorless gas CO2

So, 

XCu2+, CO32, OH

G2H2S; G1SO2; MCu; SCuOYCu2+, S2

Also,

G2H2S; G1SO2; 

MCu;  SCuO

YCu2+, S2

G1 is the Hydrogen sulfide and its acts as an oxidizing and reducing agent in the reaction.

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