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Q.

Amongst FeCl3.3H2O,  K3Fe(CN)6   and CoNH36Cl3, the spin-only magnetic moment value of the inner-orbital complex that absorbs light at shortest wavelength is __________B.M. [nearest integer]

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answer is 2.

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Detailed Solution

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FeH2O3Cl3, K3Fe(CN)6,CoNH36Cl3inner orbital complexes  

K3Fe(CN)6 has more  Δ0 than CoNH36Cl3;  as C¯N is stronger ligand. 

 More the Δ0,lesser will be the value of absorbed  λ

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 Spin only magnetic moment (μ)=3BM  

=1.732BM     Rounding off 2

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