Amongst ${\mathrm{NH}}_3,{\mathrm{PH}}_3,{\mathrm{AsH}}_3$and ${\mathrm{SbH}}_3$ the one with highest boiling point is :

 

Because SbH₃ has a greater molecular weight, the force of attraction between them is stronger. As a result, boiling point rises. Although NH₃ has a strong H-bond, SbH₃ has the greatest boiling point due to its biggest molecular weight. NH₃ has a boiling point of 238.5 K and SbH3 of 254.6 K.

${\mathrm{BiH}}_3>{\mathrm{SbH}}_3>{\mathrm{NH}}_3>{\mathrm{AsH}}_3>{\mathrm{PH}}_3$

(Order of boiling point).