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Q.

Amount of CH3CI that can be prepared from 20 g of CH4 and 10 g of Cl2 by the following reaction, is :

CH4+Cl2CH3Cl+HCl, (assume that no other reaction is taking place)

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a

15.15

b

15.44

c

10.1

d

13.23

answer is D.

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Detailed Solution

CH4+Cl2CH3Cl+HCl

One mole of methane reacts with one mole of chlorine gas. 20 g of methane has 1.25 moles of methane and 10 g of Cl2 has 0.3 moles of Cl2. This shows that Cl2 is the limiting reagent and decides the quantity of the product forms in the reaction.

One mole of Cl2 forms one mole of CH3Cl, therefore 0.3 moles of Cl2 forms 0.3 moles of CH3Cl. Amount of CH3Cl is:

0.3 mol=Mass of CH3Cl50.5 g/mol=15.15 g 

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