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Q.

Amount of Ferrous oxalate that reacts with one mole of acidified KMnO4 is___?

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a

239 gm

b

144 gm

c

288 gm

d

400 gm

answer is A.

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Detailed Solution

Writing the half reactions of reduction and oxidation,

2KMnO4+3H2SO4+5eK2SO4+2MnSO4+3H2O×3

2FeC2O4+3H2SO4Fe2SO43+3H2O+4CO2+3e×5

On adding the above two half reactions, we get the complete balanced redox reaction.

6KMnO4+24H2SO4+10FeC2O45Fe2SO43+3K2SO4+6MnSO4+24H2O+20CO2

Then number of moles of Ferrous oxalate that react with one mole of  KMnO4 is 10/6=1.66

Gram molecular weight of Ferrous oxalate is = 144 gm per mole

So, mass of Ferrous oxalate that react with one mole of KMnO4 =1.66×144=239 gram

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