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Amount of oxalic acid present in a solution can be determined by its titration with ${KMnO}_{4}$ solution in the presence of $H_{2} {SO}_{4} .$ The titration gives unsatisfactory result when carried out in the presence of HCl, because HCl

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Reduces permanganate to ${Mn}^{+ 2}$

Oxidizes oxalic acid to carbon dioxide and water

Gets oxidized by oxalic acid to chlorine

Furnishes H+ ions in addition to those from oxalic acid

answer is B.

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Detailed Solution

Oxalic acid will be oxidized, in presence of $H_{2} {SO}_{4}$ only, not in presence of HCl, because HCl gets oxidized to ${Cl}_{2} with {KMnO}_{4}$

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