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Q.

Amphoteric hydroxide react with both alkalies and acids. Which of the following group 2 metal hydroxides is soluble in sodium hydroxide?

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a

Be(OH)2

b

Mg(OH)2

c

Ca(OH)2

d

Ba(OH)2

answer is A.

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Detailed Solution

The solubility of hydroxides of alkaline earth metals increases from Be to Ba, in water. Be(OH)2 and Mg(OH)2 are almost insoluble. Due to high hydration enthalpy and high Iattice energy Be(OH)2 is not soluble in water.
Be(OH), is an amphoteric hydroxide. With acids, Be(OH), is neutralised giving salts.

Be(OH)2+2HClBeCl2+2H2O

Be(OH)2 reacts with NaOH also forming beryIlate.

Be(OH)2+2NaOHNa2BeO2+2H2O

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