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Q.

An Acid – Base indicator has ka value of 3×105  the acid form of indicator is red and basic form is blue. The [H+] required to change the indicator from 75% red to 75% blue is 

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a

105M

b

9×103M

c

4×103M

d

8×105M

answer is A.

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Detailed Solution

HIn H++InAcid                                            BaseRed                                             Blue

ka=H+InHIn

H+=ka.H  InIn

1st case Acid from 75% Base 25%

H+=3×105×7525=9×105

2nd case acid from 25% Base 75%

H+=3×105×2575=1×105

ΔH+=9×1051×105

=8×105

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