Q.

An acidic aqueous solution contains 0.02 M - FeCl2 and 0.05 M - FeCl3 , at 25° C. Now NaOH solution is added is this solution, drop by drop. The pH range in which only the precipitation of Fe(OH) is occur without precipitation of  Fe(OH)2 (s) differs by 'x' unit. The value of 'x' is given:

Ksp of Fe(OH)2=8×1016

Ksp of Fe(OH)3=4×1028

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answer is 2.

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Detailed Solution

For pptn. of Fe(OH)3,OH=4×10280.053=2×109

For pptn. of Fe(OH)2,OH=8×10160.02=2×107

Δ(pH) = 9-7 = 2

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