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Q.

An acidic solution of dichromate is electrolyzed for 8 minutes using 2A current. As per the following equation  Cr2O72+14H++6e2Cr3++7H2O. The amount of  Cr3+ obtained was 0.104 g. The efficiency of the process ( in %) is (Take F=96000C, At.mass of chromium = 52) ________

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answer is 60.

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Detailed Solution

[molesofCr3+]×3=[8×60×2]/96000           molesofCr3+=[8×4]/9600=(1/300)mol            molesofCr3+=(52/300)g

% efficiency={[Actual obtained amount]/[theoretical obtained amount]}*100

=[(0.104/(52/100))*100]=30*(104/52)=60%

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