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Q.

An acidic solution of methyl red has an absorbance of0.451 at 530 nm in a 5.00 mm cell. Calculate the molarity of methyl red in this solution.

[Molar absorptivity=1.06×105Lmol1cm1 at 530nm]

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a

2.13×106M

b

8.51×106M

c

1.05×105M

d

4.26×106M

answer is C.

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Detailed Solution

According to Beer Lambert Law

A=ebc

Where A is absorbance (no units), since

A=log10P0/P

e is the molar absorptivity with units of L mol1cm1

b is the path length (in cm) of the sample-- that is, the path length of the cuvette in which the sample is contained. We will express this measurement in centimeters.

c is the concentration of the compound in solution expressed in   mol L1

0.451=1.06×105×5×101cc=8.51×106M

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