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Q.

An alcohol contains 60% carbon and 13.3% hydrogen and gives positive iodoform test. The alcohol is

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a

2-propanol

b

1-propanol

c

2-butanol

d

1-butanol

answer is A.

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Detailed Solution

C:H:O=6012:13.31:26.716=51.67:13.31.67:1.671.67=3:8:1

The formula of the compound is C3H8O.
Since the alcohol gives positive iodoform test. It has 

CH3CH(OH)CH3

hence it is 2-propanol.

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