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Q.

An aliphatic organic compound(X) containing C, H and N on hydrolysis with dilute HCl to produce formic acid.  'X" is reduced to dimethylamine in presence of Pt (or)  Ni. The compound(X) could be 

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a

CH3NC

b

CH3CN

c

CH3NH2

d

A mixture of CH3CN and CH3NC

answer is A.

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Detailed Solution

Explanation:

  1. Hydrolysis with dilute HCl producing formic acid (HCOOH):

    Upon hydrolysis, methyl cyanide (CH3CN) reacts with water and HCl to form formic acid (HCOOH) as a byproduct:

    CH3CN + H2O + HCl → HCOOH

  2. Reduction to dimethylamine ((CH3)2NH):

    When CH3CN is reduced in the presence of Pt or Ni, the nitrile group is hydrogenated, forming dimethylamine:

    CH3CN + H2 → (CH3)2NH

  3. Analyzing other options:
    • CH3NC (Methyl isocyanide): Hydrolysis of CH3NC produces methylamine and formic acid but does not reduce to dimethylamine.
    • CH3NH2 (Methylamine): This does not undergo hydrolysis to produce formic acid.
    • A mixture of CH3CN and CH3NC: This would produce a mix of products, which is not supported by the question.

Final Answer:

The compound X is CH3CN.

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