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Q.

An amine on reaction with benzenesulphonyl chloride produces a compound insoluble in alkaline solution. This amine can be prepared by ammonolysis of ethyl chloride. The correct structure of amine is:

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a

Question Image

b

Question Image

c

$C H_{3} C H_{2} C H_{2} N H_{2}$

d

$C H_{3} C H_{2} N H_{2}$

answer is B.

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Detailed Solution

A 2° amine gives a product insoluble in alkaline solutions when treated with $C_{6} H_{5} S O_{2} C l$

But the 2° amine is obtained by ammonolysis of ethyl chloride .

$∴$ The 2° amine has to be $C H_{3} - C H_{2} - C H_{2} - N H - C H_{2} C H_{3}$

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