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Q.

An amount of 0.10 moles of AgCl is added to one liter of water. Next the crystals of NaBr are added until 80% of AgCl is converted to AgBr(s). If the  Br at this point is  Y×108 then the value of Y is ____
(Given  KSP of  AgCl=1010 and KSP of  AgBr=4×1013)

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answer is 4.

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Detailed Solution

Concept of simultaneous solubility 
80%  AgClAgBr
 AgClAg++Cl
(0.01-9)   (a+b)    a     …….(1)
AgBrAg++Br
0.08       (a+b)     b    ………(2)
 KspKsp=AgClAgBr=a+baa+bb=10104×1013
 ab=10004=250     a=250b   
Substitute a in 2 eq., for  Br   conc.,
 a+bb=4×1013 250b+bb=4×1013 250b2+b2=4×1013 251b2=4×1013 b2=15.936×1016 b=3.99×108
   So  b=4×108

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