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Q.

An aq. solution of 0.5 M KMnO4 is divided into two parts. One part of it requires 125 mL of 1.5 M aq. solution of oxalate ions m acidic medium, while another part requires 270 mL of 0.5 M aq. solution of iodide ions m neutral medium which converted into I2 only. Calculate total volume: of the initial KMnO4 solution

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answer is 240.

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Detailed Solution

Let V1 and  V2 are volumes of KMnO4 in 1st part and 2nd part

Reaction (a) KMnO4+C2O42 Neutral CO2+Mn2+

0.5×V1×5=1.5×125×2V1=150mL

Reaction (b) KMnO4+I Neutral I2+MnO2

0.5×V2×3=0.5×270×1V2=90mL

so, initial volume  =150+90=240mL

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