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Q.

An aqueous pink solution of cobalt(II) chloride changes to deep blue on addition of excess of HCI. This is because..............

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a

CoH2O62+is transformed into CoCl64

b

CoH2O62+ is transformed into CoCl42

c

tetrahedral complexes have smaller crystal field splitting than octahedral complexes

d

tetrahedral complexes have larger crystal field splitting than octahedral complex

answer is B, C.

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Detailed Solution

Cobalt (II) chloride's aqueous pink solution is caused by an electron moving from the 

CoH2O62 complex's t2g to eg energy state. If too much HCl is added, this solution.

(i) CoH2O62 is transformed into  CoCl42.

(ii) Tetrahedral complexes have smaller crystal field splitting than octahedral complexes because 

Δr=49Δ0

Hence, options B and C are correct. 

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