Q.

An aqueous solution containing 64% by weight of volatile liquid ‘A’ (molecular mass 128) has pressure of 145 mm, then vapour pressure of pure ‘A’ is ? Let ‘A’ and H2O forms ideal mixture, P0 of H2O is 155mm.

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a

105 mm 

b

145 mm 

c

21 mm 

d

150 mm 

answer is C.

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Detailed Solution

PT=PA+PH2O

145=PA0×0.2+155×0.8

PA0=105mm

nA=64128=0.5

nH2O=3618=2

χA=0.52.5=0.2

χH2O=0.8

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