Q.

An aqueous solution freezes at – 0.372oC. If Kf and Kb for water are 1.86K kg mol–1 and 0.53 K kg mol-1 respectively, the elevation in boiling point of same solution in K is :

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a

4.6

b

0.106

c

0.72

d

0.46

answer is D.

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Detailed Solution

The boiling point elevation is a colligative property of matter that is determined by the solute-to-solvent ratio but not by the nature of the solute. This implies that a solution's boiling point is influenced by the amount of solute added to the solution. The solute concentration in the solution will cause the boiling point to increase correspondingly.

Using the formula: Tb=Kb*m, the elevation in boiling point of same solution in K is 0.106.

Hence, the correct option (D). 0.106 

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