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Q.

An aqueous solution is 0.3 M in Al3+ and 3 M in Mg2+. Select the only incorrect option. 

Given: KspAl(OH)3=3×1034KspMg(OH)2=3×1012M3

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a

For selective precipitation of Al(OH)3 only, pH of solution should be 3 to 8

b

At pH = 9 both Al(OH)3 and Mg(OH)2 will precipitate

c

At pOH = 12 neither Al(OH)3 nor Mg(OH)2 will precipitate

d

Mg(OH)2 will precipitate at maximum pH = 8

answer is D.

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Detailed Solution

At pH=8,OH=106M

KipMg(OH)2=3×1012=Ksp

Hence, pH = 8 is the minimum pH.

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