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Q.

An aqueous solution of 6.3g oxalic acid dihydrate is made up to 250 mL, the volume of 0.1 N NaOH required to completely neutralize 10 mL of this solution is

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a

40 mL

b

20 mL

c

10 mL

d

4 mL

answer is A.

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Detailed Solution

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Equivalents of H2C2O42H2O=Equivalents of NaOH (At equivalence point)Strength of H2C2O42H2O(in g/L)=6.3250/1000=25.2 g/LNormality of H2C2O42H2O=StrengthEq.wt=25.263=0.4 NEq.wt.of oxalica acid=Mol.wt2=1262=63 Using normality equation:H2C2O42H2ONaOHN1V1=N2V20.4×10=0.1×V2orV2=0.4×100.1=40 mL

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An aqueous solution of 6.3g oxalic acid dihydrate is made up to 250 mL, the volume of 0.1 N NaOH required to completely neutralize 10 mL of this solution is