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Q.

An aqueous solution of a salt ‘x’ turns blood red on treatment with SCN and blue on treatment with K4[Fe(CN)6]. The compound ‘x’ also give a positive chromyl chloride test. The salt ‘x’ is ____ .

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a

Cu(NO3)2

b

Fe(NO3)3

c

FeCl3

d

CuCl2

answer is B.

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Detailed Solution

Fe+3 cation gives blood red colour with SCN1 and blue colour with K4[Fe(CN)6]

Fe3+(aq)+SCN [FeSCN]2+Paleyellow                                 Bloodred

Fe3+(aq)+K4[Fe(CN)6] Fe4[Fe(CN)6]3Paleyellow                                                      Blue

Cl anion undergoes chromyl chloride test. Hence, the salt 'X' is FeCl3

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