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Q.

An aqueous solution of colorless metal sulfate M, gives a white precipitate with NH4OH. This was soluble in excess of NH4OH. On passing H2S through this solution a white precipitate is formed. The metal M in the salt is :

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a

Zn

b

Ba

c

Ca

d

Al

answer is D.

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Detailed Solution

CoCl2+2NaHCO3CoHCO32+2NaClCoHCO32+4NaHCO3                        Na4CoCO33+3H2O+3CO2Bn2+H2O2HBr+[O]2Na4CoCO33+H2O+[O]                              2Na3CoCO33( Green )+2NaOH  (Sodium cobalticarbonate) 

Hence,  the correct option is D

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